Q. Which of the following hydrocarbons undergo addition reactions: C2H6, C3H8, C3H6, C2H2 and CH4. The hydrocarbons that undergo addition reactions are:C3H6 (propene) – has a double bond, allowing addition reactions.C2H2 (ethyne) – has a triple bond, allowing addition reactions.C2H6, C3H8, and CH4 are saturated hydrocarbons, so they don’t undergo addition reactions. Explore Entire Collection of Texcellency Books Download Your FREE Book Now “A good textbook is like a smart GPS — it doesn’t just give you the destination, it tells you every turn along the way, in simple language you actually understand.”